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I have done copper and nickel plating on motorcycle parts. Copper and precious metal is easier to do that say nickel or chrome, which involve toxic chemicals. I have never tried these pen systems. I will say that the preparation of the metal surface is key. With copper you can build up surface defects quite easily. A friend was doing gold and it was much easier than nickel. 

http://www.ferroinstant.com/

The above people seem to have commercialised things quite nicely.

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